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3 The three distinct sulphur compound classes across the vegetable kingdom glutathione, organosulphur, glucosinolates The literature describes at least three distinct families of sulphur-containing compounds across the vegetable kingdom: glutathione itself (in asparagus, avocado, spinach), the alkyl cysteine sulphoxides (in the allium family), and the glucosinolates (in the cruciferous family)

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3-Mercaptopyruvate sulfurtransferase produces potential redox regulators cysteine- and glutathione-persulfide (Cys-SSH and GSSH) together with signaling molecules H 2 S 2 , H 2 S 3 and H 2 S

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